What class of organic chemicals forms potentially explosive peroxides?

Ethers are known to form potentially explosive peroxides when they are exposed to air and light over time. This reaction typically occurs because the molecular structure of ethers allows for the formation of unstable peroxide compounds. When ethers are stored, especially if they are in opened containers or have been in use for extended periods, they can oxidize, leading to the accumulation of peroxides, which can be highly reactive and sometimes explosive upon concentration or upon reaction with certain catalysts or heat.

Understanding the chemical behavior of ethers in relation to peroxide formation is crucial for safety in laboratories and industries that utilize these substances. Proper storage and handling protocols must be established to mitigate the risks associated with explosive peroxides, emphasizing the importance of recognizing ethers as high-risk compounds in this context.

In contrast, aldehydes, cyclic hydrocarbons, and alkanes do not commonly form peroxides in a similar manner. While they can undergo various chemical reactions, their structures and reactivities do not typically lead to the formation of hazardous peroxides like those seen with ethers.